Here you will learn how to prepare Rochelle salt from baking soda and cream of tartar, which are available from a grocery store.

It will involve two chemical steps (reactions) prior to the actual growing of the crystal. The procedures are safe and can be conducted in your kitchen, with appropriate adult supervision.

The only restriction for the purposes of the Crystal Growing contest is that 200 g of cream of tartar is the MAXIMUM starting amount of that reagent that may be used to prepare a given crystal.


NOTE: Some people have gone to bulk food or health food stores where they found a less expensive cream of tartar. Unfortunately, what is sold there as "cream of tartar" frequently has been NOT potassium bitartrate, but rather a mixture of calcium sulfate (Plaster of Paris), monocalcium phosphate, fumaric acid, and corn starch. This mixture definitely WILL NOT WORK. If the sales person cannot guarantee that what they offer is potassium bitartrate, don't buy it, at least for this purpose.


This involves the conversion of baking soda (sodium bicarbonate)[NaHCO3] to sodium carbonate(washing soda)[Na2CO3]

  1. Place the contents of a 500 g box of baking soda into a suitable Pyrex container.

  2. Heat in an oven at about 150 deg F (65 deg C) for one hour.

  3. Increase the temperature to 250 deg F (120 deg C) and hold there for about an hour.

  4. Repeat this increase for 350 and 450 deg F (175 and 230 deg C), for an hour each.

  5. Remove the container and allow to cool to room temperature.

  6. Place the sodium carbonate into a sealed container until used further.


This involves the reaction of cream of tartar (potassium bitartrate formulation only)[KHC4H4O6] with sodium carbonate [Na2CO3] to produce Rochelle salt (potassium sodium tartrate)[NaKC4H4O6].

  1. Place a suspension of 200 g (7 oz) (maximum) of cream of tartar in 250 mL (one cup) of water into a beaker of at least 500 mL (2 cups) capacity.

  2. Heat the beaker by placing it into a saucepan containing water.

  3. Heat the saucepan (e.g. on a stove or laboratory hot plate) until the outer water is just simmering.

  4. Add about half a teaspoon (2.5 mL) of sodium carbonate to the beaker and stir the contents. The solution will bubble.

  5. Add more sodium carbonate stepwise until no more bubbles form.

  6. Filter the hot solution by using filter paper of a coffee filter.

  7. Concentrate the solution (by evaporation) to about 400 mL or a little less by heating.

  8. Allow the filtrate to cool and then store in a cool place for several days.

  9. Collect the resulting crystals by decantation (pouring the excess liquid into another container) or by filtration.

  10. Dry the crystals by blotting with clean filter paper or paper towelling.

  11. For a better yield, concentrate again this solution left over after step 9 by heating and repeat steps 7 to10 above.

This should yield about 210 g of Rochelle salt.


You can now recrystallize your Rochelle Salt, by using a single good crystal obtained above or by making a seed crystal.

Now go to procedures for growing single crystals.

It will be helpful to know that about 60 g of Rochelle salt will dissolve in about 100 g of water at room temperature. As you warm the water, you can dissolve more Rochelle salt.

Good luck!

This procedure is adapted from that used by Malgorzata Kaminska, an Ottawa high school student, in her Science Fair project.

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